Publications
List of publications of Dr. Nico van Eikema Hommes
2022 2021 Friedrich A. , Pahl J. , Eyselein J. , Langer J. , van Eikema Hommes N. , Görling A. , Harder S. :Magnesium-halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex In: Chemical Science 12 (2021 ), p. 2410-2418 ISSN: 2041-6520 DOI: 10.1039/d0sc06321e Gaston JJ. , Tague AJ. , Smyth JE. , Butler NM. , Willis AC. , van Eikema Hommes N. , Yu H. , Clark T. , Keller PA. :The Detosylation of Chiral 1,2-Bis(tosylamides) In: Journal of Organic Chemistry 86 (2021 ), p. 9163-9180 ISSN: 0022-3263 DOI: 10.1021/acs.joc.1c00359 2020 2019 2014 2009 2008 2007 Dees A. , Zahl A. , Puchta R. , van Eikema Hommes N. , Heinemann FW. , Ivanovic-Burmazovic I. :Water exchange on seven-coordinate Mn(II) complexes with macrocyclic pentadentate ligands: Insight in the mechanism of Mn(II) SOD mimetics In: Inorganic Chemistry 46 (2007 ), p. 2459-2470 ISSN: 0020-1669 DOI: 10.1021/ic061852o Pasgreta E. , Puchta R. , Galle M. , van Eikema Hommes N. , Zahl A. , van Eldik R. :Ligand-exchange processes on solvated lithium cations: DMSO and water/DMSO mixtures In: ChemPhysChem 8 (2007 ), p. 1315-1320 ISSN: 1439-4235 DOI: 10.1002/cphc.200600624 Pasgreta E. , Puchta R. , Galle M. , van Eikema Hommes N. , Zahl A. , van Eldik R. :Ligand Exchange Processes on Solvated Lithium Cations. II. Complexation by Cryptands in γ-Butyrolactone as Solvent In: Journal of Inclusion Phenomena and Macrocyclic Chemistry 58 (2007 ), p. 81-88 ISSN: 0923-0750 DOI: 10.1007/s10847-006-9125-y 2006 Galle M. , Puchta R. , van Eikema Hommes N. , van Eldik R. :Rational design of cation hosts - Prediction of cation selectivity by quantum chemical calculations In: Zeitschrift für Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics 220 (2006 ), p. 511-523 ISSN: 0942-9352 DOI: 10.1524/zpch.2006.220.4.511 Puchta R. , Galle M. , van Eikema Hommes N. :Protons on tour - DFT-study of H+-migration in [1.1.1]- and [2.2.2]-cryptands In: Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 61 (2006 ), p. 1327-1334 ISSN: 0932-0776 DOI: 10.1515/znb-2006-1103 Puchta R. , Meier R. , van Eikema Hommes N. , van Eldik R. :Quantum chemical analysis of the enantiomerisation mechanism of complexes of the type [M-II(XU)(4)]F+ (M = Pt, Pd, Ni; X = S, Se, Te; U = urea) In: European Journal of Inorganic Chemistry (2006 ), p. 4063-4067 ISSN: 1434-1948 DOI: 10.1002/ejic.200600483 Puchta R. , van Eikema Hommes N. , Meier R. , van Eldik R. :A new enantiomerization mechanism for tripodal penta-coordinate Zn-II(nta) complexes. Theoretical clarification of the observed H-1 NMR spectrum In: Dalton Transactions (2006 ), p. 3392-3395 ISSN: 1477-9226 DOI: 10.1039/b602792j Schiessl W. , Summa N. , Puchta R. , van Eikema Hommes N. , van Eldik R. :Thermodynamic and kinetic studies on reactions of Pt(II) complexes with biologically relevant nucleophiles In: Inorganic Chemistry 45 (2006 ), p. 2948-2959 ISSN: 0020-1669 DOI: 10.1021/ic051955r 2005 Castro C. , Chen Z. , Wannere C. , Jiao H. , Karney W. , Mauksch M. , Puchta R. , van Eikema Hommes N. , Schleyer P. :Investigation of a putative Mobius aromatic hydrocarbon. The effect of benzannelation on Mobius [4n]annulene aromaticity In: Journal of the American Chemical Society 127 (2005 ), p. 2425-2432 ISSN: 0002-7863 DOI: 10.1021/ja0458165 Illner P. , Zahl A. , Puchta R. , van Eikema Hommes N. , Wasserscheid P. , van Eldik R. :Mechanistic studies on the formation of Pt(II) hydroformylation catalysts in imidazolium-based ionic liquids In: Journal of Organometallic Chemistry 690 (2005 ), p. 3567-3576 ISSN: 0022-328X DOI: 10.1016/j.jorganchem.2005.03.029 Puchta R. , van Eikema Hommes N. , van Eldik R. :Evidence for interchange ligand-exchange processes on solvated beryllium cations In: Helvetica Chimica Acta 88 (2005 ), p. 911-922 ISSN: 0018-019X DOI: 10.1002/hlca.200590085 Scheurer A. , Maid H. , Hampel F. , Saalfrank R. , Toupet L. , Mosset P. , Puchta R. , van Eikema Hommes N. :Influence of the conformation of salen complexes on the stereochemistry of the asymmetric epoxidation of olefins In: European Journal of Organic Chemistry (2005 ), p. 2566-2574 ISSN: 1434-193X DOI: 10.1002/ejoc.200500042 Schiessl W. , Summa N. , Weber C. , Gubo S. , Dücker-Benfer C. , Puchta R. , van Eikema Hommes N. , van Eldik R. :Experimental and theoretical approaches to the protonation of thiourea: A convenient nucleophile in coordination chemistry revisited In: Zeitschrift für Anorganische und Allgemeine Chemie 631 (2005 ), p. 2812-2819 ISSN: 0044-2313 DOI: 10.1002/zaac.200500157 Weber C. , Puchta R. , van Eikema Hommes N. , Wasserscheid P. , van Eldik R. :Transition-state effects of ionic liquids in substitution reactions of Pt-II complexes In: Angewandte Chemie International Edition 44 (2005 ), p. 6033-6038 ISSN: 1433-7851 DOI: 10.1002/anie.200501329 van Eikema Hommes N. , Clark T. :Regression formulae for ab initio and density functional calculated chemical shifts In: Journal of Molecular Modeling 11 (2005 ), p. 175-185 ISSN: 1610-2940 DOI: 10.1007/s00894-004-0223-8 2004 Dosche C. , Kumke M. , Löhmannsröben HG. , Ariese F. , Bader A. , Gooijer C. , Miljanic O. , Iwamoto M. , Vollhardt P. , Puchta R. , van Eikema Hommes N. :Deuteration effects on the vibronic structure of the fluorescence spectra and the internal conversion rates of triangular [4]phenylene In: Physical Chemistry Chemical Physics 6 (2004 ), p. 5476-5483 ISSN: 1463-9076 DOI: 10.1039/b414545c Puchta R. , Galle M. , van Eikema Hommes N. , Pasgreta E. , van Eldik R. :Evidence for associative ligand exchange processes on solvated lithium cations In: Inorganic Chemistry 43 (2004 ), p. 8227-8229 ISSN: 0020-1669 DOI: 10.1021/ic0487979 Saalfrank R. , Deutscher C. , Maid H. , Ako AM. , Sperner S. , Nakajima T. , Bauer W. , Hampel F. , Heß BA. , van Eikema Hommes N. , Puchta R. , Heinemann FW. :Synthesis, structure, and dynamics of six-membered metallacoronands and metallodendrimers of iron and indium In: Chemistry - A European Journal 10 (2004 ), p. 1899-1905 ISSN: 0947-6539 DOI: 10.1002/chem.200306050 Scheurer A. , Bauer W. , Hampel F. , Schmidt C. , Saalfrank R. , Mosset P. , Puchta R. , van Eikema Hommes N. :Desymmetrisation of C-2-symmetric (2S,3S)-diazidobutane-1,4-diol with benzaldehyde In: Tetrahedron-Asymmetry 15 (2004 ), p. 867-872 ISSN: 0957-4166 DOI: 10.1016/j.tetasy.2004.01.027 2003 Dosche C. , Kumke M. , Ariese F. , Bader A. , Gooijer C. , Dosa P. , Han S. , Miljanic O. , Vollhardt P. , Puchta R. , van Eikema Hommes N. :Shpol'skii spectroscopy and vibrational analysis of [N]phenylenes In: Physical Chemistry Chemical Physics 5 (2003 ), p. 4563-4569 ISSN: 1463-9076 DOI: 10.1039/b308036f 2002 Glaser H. , Puchta R. , van Eikema Hommes N. , Leusser D. , Murso A. , Stalke D. , Bauer W. , Saalfrank R. :A domino aldol addition/hemiketal formation/hemiketal formation/epimerization route to a heteroadamantane. A crystal-structure, NMR, and computational study In: Helvetica Chimica Acta 85 (2002 ), p. 3828-3841 ISSN: 0018-019X DOI: 10.1002/1522-2675(200211)85:113.0.CO;2-Z Jiao H. , van Eikema Hommes N. , Schleyer P. :Can bridged 1,6-X-[10]annulenes (X = SiH2, SiMe2, PH, and S) exist? In: Organic Letters 4 (2002 ), p. 2393-2396 ISSN: 1523-7060 DOI: 10.1021/ol026144v 2001 2000 1998 Cyranski M. , Krygowski T. , Wisiorowski M. , van Eikema Hommes N. , Schleyer P. :Global and local aromaticity in porphyrins: An analysis based on molecular geometries and nucleus-independent chemical shifts In: Angewandte Chemie International Edition 37 (1998 ), p. 177-180 ISSN: 1433-7851 DOI: 10.1002/(SICI)1521-3773(19980202)37:1/23.0.CO;2-H Hampel F. , van Eikema Hommes N. , Hoops S. , Maaref F. , Schobert R. :Novel nine-membered titanaheterocycles - Structure, ab initio calculations, and preparative use towards the selective synthesis of substituted cyclopentanols In: European Journal of Inorganic Chemistry (1998 ), p. 1253-1262 ISSN: 1434-1948 DOI: 10.1002/(SICI)1099-0682(199809)1998:93.0.CO;2-H 1997 Mauser H. , Hirsch A. , van Eikema Hommes N. , Clark T. , Pietzak B. , Weidinger A. , Dunsch L. :Stabilization of Atomic Nitrogen Inside C60 In: Angewandte Chemie (International Edition in English) 36 (1997 ), p. 2835-2838 ISSN: 0570-0833 DOI: 10.1002/anie.199728351 Mauser H. , van Eikema Hommes N. , Hirsch A. , Clark T. :Chemistry of Convex versus Concave Carbon: The Reactive Exterior and the Inert Interior of C60 In: Journal of Molecular Modeling 3 (1997 ), p. 415-422 ISSN: 0948-5023 DOI: 10.1007/s008940050059 Schleyer P. , Jiao H. , van Eikema Hommes N. , Malkin V. , Malkina O. :An evaluation of the aromaticity of inorganic rings: Refined evidence from magnetic properties In: Journal of the American Chemical Society 119 (1997 ), p. 12669-12670 ISSN: 0002-7863 DOI: 10.1021/ja9719135 1996 Bickelhaupt M. , van Eikema Hommes N. , Fonseca Guerra C. , Baerends EJ. :The carbon-lithium electron pair bond in (CH3Li)(n) (n=1, 2, 4) In: Organometallics 15 (1996 ), p. 2923-2931 ISSN: 0276-7333 DOI: 10.1021/om950966x Jiao H. , van Eikema Hommes N. , Schleyer P. , de Meijere A. :[5]Pericyclynes are not homoaromatic In: Journal of Organic Chemistry 61 (1996 ), p. 2826-2828 ISSN: 0022-3263 DOI: 10.1021/jo952028c Schleyer P. , Maerker C. , Dransfeld A. , Jiao H. , van Eikema Hommes N. :Nucleus-independent chemical shifts: A simple and efficient aromaticity probe In: Journal of the American Chemical Society 118 (1996 ), p. 6317-6318 ISSN: 0002-7863 DOI: 10.1021/ja960582d van Eikema Hommes N. :Organometallic Chemistry in the Computer, Ab-Initio/DFT Computations In: J. Gasteiger (Ed.) (ed.): Software-Entwicklung in der Chemie 10; Software Development in Chemistry 10 , Frankfurt am Main : GDCh Gesellschaft Deutscher Chemiker , 1996 , p. 159-173 ISBN: 3-924763-57-7 1995 1994 Harder S. , van Lenthe J. , van Eikema Hommes N. , Schleyer P. :NUCLEOPHILIC RING-OPENING OF EPOXIDES BY ORGANOLITHIUM COMPOUNDS - AB-INITIO MECHANISMS In: Journal of the American Chemical Society 116 (1994 ), p. 2508-2514 ISSN: 0002-7863 DOI: 10.1021/ja00085a035 Hoffmann D. , Bauer W. , Hampel F. , van Eikema Hommes N. , Schleyer P. , Otto P. , Pieper U. , Stalke D. , Wright D. , Snaith R. :ETA(3) AND ETA(6) BRIDGING CATIONS IN THE N,N,N',N'',N''-PENTAMETHYLDIETHYLENETRIAMINE-SOLVATED COMPLEXES OF BENZYLPOTASSIUM AND BENZYLRUBIDIUM - AN X-RAY, NMR, AND MO STUDY In: Journal of the American Chemical Society 116 (1994 ), p. 528-536 ISSN: 0002-7863 DOI: 10.1021/ja00081a013 Pritzkow H. , Lobreyer T. , Sundermeyer W. , van Eikema Hommes N. , Schleyer P. :INVERSELY COORDINATING SILANIDE IONS IN AN OLIGOMERIC SODIUM ALCOHOLATE In: Angewandte Chemie (International Edition in English) 33 (1994 ), p. 216-217 ISSN: 0570-0833 DOI: 10.1002/anie.199402161 van Eikema Hommes N. , Schleyer P. :MECHANISMS OF AROMATIC LITHIATION INFLUENCE OF AGGREGATION AND DIRECTING GROUPS In: Tetrahedron 50 (1994 ), p. 5903-5916 ISSN: 0040-4020 1993 Anders E. , Opitz A. , van Eikema Hommes N. , Hampel F. :PICOLINE AND TOLUENE - A COMPARISON OF STRUCTURAL-PROPERTIES AND RELATIVE STABILITIES OF THEIR MONOLITHIATED DERIVATIVES In: Journal of Organic Chemistry 58 (1993 ), p. 4424-4430 ISSN: 0022-3263 DOI: 10.1021/jo00068a043 Glukhovtsev M. , Schleyer P. , van Eikema Hommes N. , Minkin V. :ARE THE C4V COMPLEXES OF CYCLOBUTADIENE WITH CO, NO+, AND CS MINIMA In: Chemical Physics Letters 205 (1993 ), p. 529-534 ISSN: 0009-2614 DOI: 10.1016/0009-2614(93)80008-D Glukhovtsev M. , Schleyer P. , van Eikema Hommes N. , Walkimar de M. Carneiro J. , Koch W. :IS TETRAHEDRAL H-4(2+) A MINIMUM - ANOMALOUS BEHAVIOR OF POPULAR BASIS-SETS WITH THE STANDARD P-EXPONENTS ON HYDROGEN In: Journal of Computational Chemistry 14 (1993 ), p. 285-294 ISSN: 0192-8651 DOI: 10.1002/jcc.540140305 Heidrich D. , van Eikema Hommes N. , Schleyer P. :AB-INITIO MODELS FOR MULTIPLE-HYDROGEN EXCHANGE - COMPARISON OF CYCLIC 4-CENTER AND 6-CENTER SYSTEMS In: Journal of Computational Chemistry 14 (1993 ), p. 1149-1163 ISSN: 0192-8651 DOI: 10.1002/jcc.540141005 1992 Boche G. , Fraenkel G. , Cabral J. , Harms K. , van Eikema Hommes N. , Lohrenz J. , Marsch M. , Schleyer P. :EXO,EXO-[1,3-BIS(TRIMETHYLSILYL)ALLYL]LITHIUM N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE COMPLEX - CRYSTAL-STRUCTURE AND DYNAMICS IN SOLUTION In: Journal of the American Chemical Society 114 (1992 ), p. 1562-1565 ISSN: 0002-7863 DOI: 10.1021/ja00031a004 Boese R. , Bläser D. , Niederprüm N. , Nüsse M. , Brett W. , Schleyer P. , Bühl M. , van Eikema Hommes N. :LARGE HYPERCONJUGATIVE AND INDUCTIVE EFFECTS ON C-C-X BOND ANGLES (X = MAIN-GROUP ELEMENT) - THE CRYSTAL-STRUCTURE OF TRIETHYLBORANE AND ABINITIO INVESTIGATIONS In: Angewandte Chemie (International Edition in English) 31 (1992 ), p. 314-316 ISSN: 0570-0833 DOI: 10.1002/anie.199203141 Dorigo A. , van Eikema Hommes N. , Krogh-Jespersen K. , Schleyer P. :THE ISOMERS OF THE ACETYLENE DERIVATIVES C2LI4 - TRANSFERABLE STRUCTURAL UNITS IN HYPERLITHIATED COMPOUNDS In: Angewandte Chemie (International Edition in English) 31 (1992 ), p. 1602-1603 ISSN: 0570-0833 DOI: 10.1002/anie.199216021 Klumpp G. , Luitjes H. , Schakel M. , de Kanter F. , Schmitz R. , van Eikema Hommes N. :N-LITHIOMETHYL-N,N'N'N''-TETRAMETHYLDIETHYLENETRIAMINE - THE 1ST-ALKYLLITHIUM COMPOUND WHICH IS MONOMERIC IN HYDROCARBONS In: Angewandte Chemie (International Edition in English) 31 (1992 ), p. 633-635 ISSN: 0570-0833 DOI: 10.1002/anie.199206331 van Eikema Hommes N. , Schleyer P. :KINETICALLY ENHANCED METALATION - HOW SUBSTITUENTS DIRECT ORTHO LITHIATION In: Angewandte Chemie International Edition 31 (1992 ), p. 755-758 ISSN: 1433-7851 van Eikema Hommes N. , Schleyer P. , Wu YD. :MECHANISM OF THE ZIEGLER DILITHIOMETHANE SYNTHESIS - AN ABINITIO STUDY OF METHYLLITHIUM PYROLYSIS In: Journal of the American Chemical Society 114 (1992 ), p. 1146-1151 ISSN: 0002-7863 1991 Bühl M. , van Eikema Hommes N. , Schleyer P. , Fleischer U. , Kutzelnigg W. :APPLICATIONS AND EVALUATIONS OF IGLO CHEMICAL-SHIFT CALCULATIONS FOR ORGANOLITHIUM COMPOUNDS In: Journal of the American Chemical Society 113 (1991 ), p. 2459-2465 ISSN: 0002-7863 DOI: 10.1021/ja00007a017 van Eikema Hommes N. , Bickelhaupt F. , Klumpp G. :DILITHIUM DIPHENYLMETHANEDIIDE - GENERATION, REDOX RELATIONSHIP WITH LITHIUM CHLORODIPHENYLMETHANIDE, IMPLICATION WITH REGARD TO AGGREGATION In: Journal of the Chemical Society - Series Chemical Communications (1991 ), p. 438-440 ISSN: 0022-4936 van Eikema Hommes N. , Bühl M. , Schleyer P. , Wu YD. :A COMPARATIVE THEORETICAL-STUDY OF THE ALLYL ALKALI-METALS In: Journal of Organometallic Chemistry 409 (1991 ), p. 307-320 ISSN: 0022-328X van Eikema Hommes N. , Schleyer P. :3-CENTER TRANSITION STRUCTURES FOR ALKENE HYDROBORATION AND ALKYLBORANE REARRANGEMENT In: Journal of Organic Chemistry 56 (1991 ), p. 4074-4076 ISSN: 0022-3263 1989 1988 van Eikema Hommes N. , Bickelhaupt F. , Klumpp G. :1,2-BIS(HALOMAGNESIO) ETHANE In: Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands 107 (1988 ), p. 393-394 ISSN: 0165-0513 van Eikema Hommes N. , Bickelhaupt F. , Klumpp G. :1,2-DILITHIOETHANE FROM ETHYLENE AND LITHIUM In: Angewandte Chemie (International Edition in English) 27 (1988 ), p. 1083-1084 ISSN: 0570-0833 van Eikema Hommes N. , Bickelhaupt F. , Klumpp G. :SYNTHESIS AND REACTIVITY OF BIS(TRIMETHYLSILYL)DILITHIOMETHANE In: Tetrahedron Letters 29 (1988 ), p. 5237-5240 ISSN: 0040-4039 1987 Vos M. , de Kanter F. , Schakel M. , van Eikema Hommes N. , Klumpp G. :3-LITHIO-1,5-DIMETHOXYPENTANE - PROGNOSTICATION, PREPARATION, AND SOME PROPERTIES OF A DIMERIC ALKYLLITHIUM In: Journal of the American Chemical Society 109 (1987 ), p. 2187-2188 ISSN: 0002-7863 DOI: 10.1021/ja00241a050 van Eikema Hommes N. , Bickelhaupt F. , Klumpp G. :A NEW APPROACH TO 1,2-DILITHIOETHANE - EASY PREPARATION OF DILITHIOMETHANE In: Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands 106 (1987 ), p. 514-515 ISSN: 0165-0513 1986 1983 1982